alexa Optimal TBHP allylic oxidation of Delta5-steroids catalyzed by dirhodium caprolactamate.
Diabetes & Endocrinology

Diabetes & Endocrinology

Journal of Steroids & Hormonal Science

Author(s): Choi H, Doyle MP

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Abstract Dirhodium caprolactamate is the most efficient catalyst for the oxidation of Delta5-steroids to 7-keto-Delta5-steroids by 70\% tert-butyl hydroperoxide in water (T-HYDRO). Isolated product yields range from 38 to 87\%.
This article was published in Org Lett and referenced in Journal of Steroids & Hormonal Science

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