alexa Oxidative transformation of aryls using molybdenum pentachloride.
Chemistry

Chemistry

Organic Chemistry: Current Research

Author(s): Waldvogel SR, Trosien S

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Abstract Molybdenum pentachloride combines a strong Lewis acid character with an unusually high oxidation potential creating a powerful reagent for oxidative transformations. Since the oxidative coupling reaction of aryls is induced at an extraordinarily high reaction rate, a variety of labile groups, e.g. iodo, tert-alkyl, etc., are tolerated on the aromatic core. Furthermore, the co-formed molybdenum salts can either be exploited for template effects to obtain uncommon geometries in a preferred manner, or redox-play starts after aqueous workup. Therefore MoCl(5) represents a unique and easily available reagent. This article was published in Chem Commun (Camb) and referenced in Organic Chemistry: Current Research

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