alexa Reversal of facial selectivity in complex Diels-Alder reactions.
Bioinformatics & Systems Biology

Bioinformatics & Systems Biology

Journal of Theoretical and Computational Science

Author(s): Funel JA, Ricard L, Prunet J

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Abstract A complex Diels-Alder reaction between a semi-cyclic diene with allylic silyloxy substituents and a bromo enone presented an unusual diastereoselectivity: attack of the diene occured on its more hindered face, and this reversal of selectivity was shown to be induced by the presence of a bromo substituent in the dienophile. This article was published in Chem Commun (Camb) and referenced in Journal of Theoretical and Computational Science

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