alexa Selective synthesis of gem-chlorofluorinated nitrogen-containing derivatives after superelectrophilic activation in superacid HF SbF5.


Journal of Addiction Research & Therapy

Author(s): Liu F, MartinMingot A, Jouannetaud MP, Bachmann C, Frapper G,

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Abstract The first direct selective synthesis of novel gem-chlorofluorinated nitrogen-containing building blocks in superacid is reported. The dramatic role of the chlorine atom on the reaction is shown by in situ NMR experiments and allows the involvement of a novel original superelectrophilic activation process in superacid HF/SbF(5) to be postulated. This article was published in J Org Chem and referenced in Journal of Addiction Research & Therapy

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