alexa Solvent effects in hydrogen abstraction from cholesterol by benzophenone triplet excited state.
Diabetes & Endocrinology

Diabetes & Endocrinology

Journal of Steroids & Hormonal Science

Author(s): Andreu I, Palumbo F, Tilocca F, Morera IM, Bosc F,

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Abstract Hydrogen abstraction from the C-7 position of cholesterol (Ch) by triplet excited benzophenone (BZP) exhibits remarkable solvent-dependence in product studies. Kinetic measurements on the intramolecular version of the process in dyads containing covalently linked Ch and BZP units reveal important solvent effects and significant stereodifferentiation. © 2011 American Chemical Society This article was published in Org Lett and referenced in Journal of Steroids & Hormonal Science

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