alexa Surpassing the use of copper in the click functionalization of polymeric nanostructures: a strain-promoted approach.


Organic Chemistry: Current Research

Author(s): Lallana E, FernandezMegia E, Riguera R

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Abstract The limitations (depolymerization and Cu contamination) in the use of Cu(I)-catalyzed azide-alkyne [3 + 2] cycloadditions (CuAAC) for the selective click functionalization of polysaccharide-based systems have been efficiently surpassed using a strain-promoted approach (SPAAC). The SPAAC decoration of chitosan-g-poly(ethylene glycol) nanostructures with an immunoglobulin G under physiological conditions represents a step forward in the preparation of immunonanoparticles. This article was published in J Am Chem Soc and referenced in Organic Chemistry: Current Research

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