alexa Unexpected reactions of [60]fullerene involving tertiary amines and insight into the reaction mechanisms.
Materials Science

Materials Science

Journal of Nanomedicine & Nanotechnology

Author(s): Wang GW, Chen XP, Cheng X

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Abstract Thermal reactions of [60]fullerene with amino acid ester hydrochlorides and triethylamine in o-dichlorobenzene at reflux afforded pyrrolidinofullerene derivatives containing the CH(3)CH moiety and originating from triethylamine through an unusual C-N bond cleavage. Detailed investigation of these thermal reactions resulted in the discovery of unprecedented reactions between C(60) and tertiary amines and of reactions of C(60) with tertiary amines and aldehydes, giving cyclopentafullerene derivatives with high stereoselectivity. Plausible reaction mechanisms for the product formation involving the uncommon C-N bond cleavage of tertiary amines were proposed on the basis of extensive experimental results. This article was published in Chemistry and referenced in Journal of Nanomedicine & Nanotechnology

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