Author(s): Ronconi L, Sadler PJ
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Abstract UVA-induced photodecomposition of a Pt(IV)-diazido complex involves not only reduction to Pt(II) and N(2) release, but also O(2) evolution and formation of nitrene intermediates, whose trapping with (CH(3))(2)S gives rise to an unusual N,N'-bis(ethyl)sulfurousdiamide ligand in an apparently unprecedented process involving C-C bond formation.
This article was published in Chem Commun (Camb)
and referenced in Biochemistry & Pharmacology: Open Access