alexa Abstract | Anthracene Oxidation in an Aqueous Sodium Hypochlorite Solution

Journal of Organic & Inorganic Chemistry
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Abstract

Anthracene was used as a model compound for condensed aromatics in coals and liquid fuels. Its oxidation in aqueous sodium hypochlorite solution at 30°C, 40°C and 50°C was investigated, respectively. The results from gas chromatography/ mass spectrometry analysis show that anthracene can be converted to 22 products completely within 48 h. Non-chloro-substituted compounds are the main products and their total yield is much higher than that of chloro-substituted compounds, especially in the reaction for 96 h. Anthraquinone is the most abundant product and its yield reached maximum in the oxidation for 96 h at 40°C. The mechanisms for anthracene oxidation and chlorination are discussed.

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Author(s): LiMan Qie XianYong Wei JinNa Li Qing Wei ZhiMin Zong Jie Lv HaiYun Lu XingZhen Qi GuiZhen Gong ZiShuo Yao FangJing Liu Xing Fan and Wei Zhao

Keywords

Anthracene, Aqueous sodium hypochlorite solution, Superoxide anion radical, Oxidation, chlorination, Stereochemistry,Organometallic Compounds,Green Chemistry

 
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