alexa Abstract | Investigations of the optical spectra and EPR parameters for VO2+ ion in Na3C6H5O7·2H2O powders

Der Chemica Sinica
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Research Article Open Access

Abstract

The optical spectrum band positions and EPR parameters (g factors g//, g^ and hyperfine structure constants A// and A^) for VO2+ in Na3C6H5O7·2H2O powders are calculated from compl- ete diagonalization method and perturbation theory method. The theoretical results from both me- thods are in good agreement with the experimental values. The negative signs of hyperfine struc- ture constants A// and A^ for VO2+ in Na3C6H5O7·2H2O powder are suggested from the calcul- ations

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Author(s): GuoHao Jianga JiZi Linb Zheng Ruia and Yang Lia

Keywords

Electron paramagnetic resonance (EPR), Crystal-fields and Spin Hamiltonians, VO2+, Na3C6H5O7·2H2O, chemistry

 
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