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Research Article Open Access
Structural properties of liquid mixture related thermodynamic behavior in terms of liquid clusters are considered using third Khasare EOS. Unique solution is obtained by introducing order parameterÃ¯ÂÂ Ã¯ÂÂºÃ¯ÂÂ Ã¯ÂÂ¨Ã¯ÂÂ°Ã¯ÂÂ¼Ã¯ÂÂºÃ¯ÂÂ¼Ã¯ÂÂ±Ã¯ÂÂ Ã¯ÂÂ»Ã¯ÂÂ Ã¯ÂÂ Ã¯ÂÂ Ã¯ÂÂºÃ¯ÂÂ 1Ã¯ÂÂ Ã¯ÂÂ°Ã¯ÂÂ Ã¯ÂÂ maximum ordering) on the mathematical groundÃ¯ÂÂ Ã¯ÂÂ¬Ã¯ÂÂ in numerical computations. The choice of order parameter can strongly influence the composition of clusters. Temperature range for all computations is set between, 288.16 K to 333.16 K. The value of Ã¯ÂÂºÃ¯ÂÂÃ¯ÂÂ±Ã¯ÂÂ is attributed to variations in cluster size over entire mole fraction. Calculations are drawn on sample data for ultrasonic wave velocity, density, volume expansion coefficient and ratio of specific heat (1.3).
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Author(s): S B Khasare Milind S Deshpande and Vrushali S Khasare
Equation of State, LJ Potential, Computer Algebra, Molecular Clusters., Computer Algebra