alexa Abstract | Kinetics and mechanism of Os(VIII) catalysed oxidation of 2-methyl cyclohexanol by alkaline chloramine-T

Journal of Chemical and Pharmaceutical Research
Open Access

OMICS International organises 3000+ Global Conferenceseries Events every year across USA, Europe & Asia with support from 1000 more scientific Societies and Publishes 700+ Open Access Journals which contains over 50000 eminent personalities, reputed scientists as editorial board members.

Open Access Journals gaining more Readers and Citations

700 Journals and 15,000,000 Readers Each Journal is getting 25,000+ Readers

This Readership is 10 times more when compared to other Subscription Journals (Source: Google Analytics)

Original Articles Open Access

Abstract

The kinetics of Os(VIII) catalysed oxidation of 2-methyl cyclohexanol by alkaline chloramine-T has been investigated. The result indicates zero order kinetics with respect to 2-methyl cyclohexanol and first order kinetics with respect to chloramine-T, OH – and Os(VIII) concentrations. There is insignificant effect of ionic strength, para-toluene sulphonamide (PTS) and KCl on reaction rate. The dielectric constant of the medium shows positive effect. Elevation of temperature increases the rate of reaction in oxidation of 2-methyl cyclohexanol. A suitable mechanism in conformity with the above observation has been proposed.

To read the full article Peer-reviewed Article PDF image

Author(s): R A Singh Kamini Singh and S K Singh

Keywords

Kinetics, mechanism, oxidation, 2-methyl cyclohexanol, osmium tetroxide (OsO4), chloramine-T (CAT), alkaline medium.

 
Peer Reviewed Journals
 
Make the best use of Scientific Research and information from our 700 + peer reviewed, Open Access Journals
International Conferences 2017-18
 
Meet Inspiring Speakers and Experts at our 3000+ Global Annual Meetings

Contact Us

 
© 2008-2017 OMICS International - Open Access Publisher. Best viewed in Mozilla Firefox | Google Chrome | Above IE 7.0 version
adwords