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Original Articles Open Access
Crystallization of stable polymorphs of glycine was carried out from aqueous solution in the presence of novel metal nanaoparticles. Even lower concentration of novel metal nanaoparticles yield α and γ mixed nucleation. When the silver nanoparicles volume concentration reached 10%, the solution yield γ nucleation totally. The UV-vis spectra and Raman spectra have proved that glycine interact with the negative silver with amino cation. The interaction effectively prevent the formation of glycine alpha crystal type double-layer structure, thus inhibiting the formation of alpha crystal form, promotes the formation of gamma crystalline.
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Author(s): TianhuaChen and FeiLu
Glycine, polymorphism, additive, novel metal paricles, Metal