alexa Abstract | Synthesis, characterization and potentiometric study on stability of N-[2-hydroxy-1-napthalydene]-2-methylanilline complexes with transition elements

Journal of Chemical and Pharmaceutical Research
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Abstract

Organic ligand N-[2-hydroxy-1-napthalydene]-2-methylanilline (3) was obtained by the condensation of 2-hydroxy- 1-napthalydene (1)with 2-methylanilline (2). Formation of Schiff base (3) confirmed by TLC, M.P., IR and C,H,N analysis. Further formation of complexes of transition elements like Mn(II), CO(II), Ni(II), Cu(II) and Zn(II) with organic ligand N-[2-hydroxy-1-napthalydene]-2-methylanilline was studied by the potentiometric technique at 27±0.10C in 60%(v/v) Dioxane - water medium at 0.1M (NaClO4) ionic strength. The stability constants of N-[2- hydroxy-1-napthalydene]-2-methylanilline with transition elements were evaluated and Order of stability constant found as Cu >Co > Zn >Ni > Mn.

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Author(s): Shivaji Jadhava Megha Raia Farooque Basheer Ansarib and R K Pardeshic

Keywords

Schiff base, Transition elements, Potentiometric technique and Stability constant, potentiometric study

 
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