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Biography

Yu-Wu Zhong obtained his Ph.D. in July 2004 from the Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences (CAS) under the supervision of Prof. Guo-Qiang Lin. From September 2004 to September 2006, he has been a postdoctoral researcher at the University of Tokyo with Prof. Eiichi Nakamura. From October 2006 to September 2009, he worked with Prof Hector D. Abruna at Cornell University as a postdoctoral researcher. In October 2009, he was awarded by the “100 talent” program of CAS and joined Key Laboratory of Photochemistry of the Institute of Chemistry, CAS, to start his independent career. His research interests focus on electro-active and photofunctional organic materials and transition-metal complexes. He has published more that 110 peer-reviewed papers to date. He is currently an associate editor of RSC Advances and editorial board member of Scientific Reports and Science China Chemistry.

Abstract

Electro-active and electrochromic materials have received a wide range of applications. The incorporation of a metal ion gives rise to new functions that are not present in common organic materials. However, the applications of electro-active organometallic materials are often hampered by their high redox potentials and difficulty in film formation. Recently, we have been interested in the design and construction of electro-active systems with cyclometalated ruthenium and triarylamine as the charge-bearing sites. These materials show strong electronic coupling and multiple reversible redox processes in low positive potential window. After modified with vinyl or triphenyl units, these can be smoothly deposited onto ITO electrode surfaces by in situ electropolymerization. The obtained films exhibit multistate NIR electrochromism with long retention time, good contrast ratio, and low switching potential. The response is about a few seconds. Depending on the number of redox sites, 3 - 5 step redox switching were realized. These films have been used for the demonstrations of flip-flop or flip-flap-flop memory with electrochemical potentials as input signals and absorbance at different wavelengths as output signals. In addition to electropolymerized films, self-assembled monolayer films of these complexes were obtained and they are useful in molecular-scale NIR electrochromism and electrochemically-gated single molecular conductance.