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| Figure 5: Logarithmic values of first-order rate versus pH plot for autoxidation of the isolated α (αp-MB) and β (βp-MB) chains with a reference to the relevant values (kAf and kAs) of the parent molecules, redrawn from Sugawara et al. [34]. Conditions: the concentration of isolated α and β chains was 50 μM (in heme contents); the reaction rate was measured in 0.1 M buffer at 37°C. |
