Using Coats–Redfern equation Stage Decomposition range (°C) A(S-1) Ea(kJ/mol) ΔH(kJ/mol) ΔS (kJ/mol K) ΔG (kJ/mol ) 1st 468 3.00×109 43.35 53.28 −0.031 163 2nd 574 5.48×1011 72.87 73.42 −0.076 182 3rd 798 2.86×106 113.76 104.96 −0.097 195 UsingHorowitz–Metzger equation 1st 468 2.99×109 43.33 114.48 −0.032 164 2nd 574 5.49×1011 72.26 72.98 −0.076 181 3rd 798 2.88×106 114.48 105.04 −0.097 193 UsingPiloyan–Novikova equation 1st 468 3.05×109 42.78 54.16 −0.028 165 2nd 574 5.47×1011 71.98 73.48 −0.076 183 3rd 798 2.89×106 114.33 105.07 −0.098 194 Using Coats–Redfern equation Stage Decomposition range (°C) A(S-1) Ea(kJ/mol) ΔH(kJ/mol) ΔS (kJ/mol K) ΔG (kJ/mol ) 1st 468 3.00×109 43.35 53.28 −0.031 163 2nd 574 5.48×1011 72.87 73.42 −0.076 182 3rd 798 2.86×106 113.76 104.96 −0.097 195 UsingHorowitz–Metzger equation 1st 468 2.99×109 43.33 114.48 −0.032 164 2nd 574 5.49×1011 72.26 72.98 −0.076 181 3rd 798 2.88×106 114.48 105.04 −0.097 193 UsingPiloyan–Novikova equation 1st 468 3.05×109 42.78 54.16 −0.028 165 2nd 574 5.47×1011 71.98 73.48 −0.076 183 3rd 798 2.89×106 114.33 105.07 −0.098 194

Table 3: Kinetic parameters of [Cu(L)(OAc)]2

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