|
Sensors |
Taken
mg |
Recovery
(%) |
RSD
(%) |
Recovery
(%) |
RSD
(%) |
Recovery
(%) |
RSD
(%)
|
Recovery
(%) |
RSD
(%)
|
|
Standard addition method |
Pure solutions |
Ns-ST |
1.52 |
99.9 |
0.33 |
98.9 |
0.41 |
99.3 |
0.51 |
99.6 |
0.18 |
|
3.03 |
99.8 |
0.25 |
99.0 |
0.29 |
99.7 |
0.35 |
99.8 |
0.32 |
|
4.55 |
99.6 |
0.13 |
98.7 |
0.37 |
99.4 |
0.44 |
99.6 |
0.39 |
|
Ns-SM |
1.52 |
99.2 |
0.51 |
98.9 |
0.61 |
99.5 |
0.28 |
99.8 |
0.55 |
|
3.03 |
99.1 |
0.40 |
98.7 |
0.37 |
99.3 |
0.43 |
99.7 |
0.71 |
|
4.55 |
99.0 |
0.36 |
98.0 |
0.64 |
99.0 |
0.37 |
99.5 |
0.54 |
|
Ds-PT |
1.52 |
99.5 |
0.23 |
98.7 |
0.33 |
99.6 |
0.41 |
99.4 |
0.40 |
|
3.03 |
99.3 |
0.37 |
98.6 |
0.50 |
98.5 |
0.60 |
99.6 |
0.27 |
|
4.55 |
99.7 |
0.28 |
98.3 |
0.48 |
99.1 |
0.38 |
99.3 |
0.30 |
|
Ds-PM |
1.52 |
99.1 |
0.57 |
98.3 |
0.26 |
99.0 |
0.60 |
99.5 |
0.46 |
|
3.03 |
99.4 |
0.35 |
99.1 |
0.33 |
99.1 |
0.68 |
99.6 |
0.70 |
|
4.55 |
99.2 |
0.39 |
98.5 |
0.54 |
99.3 |
0.58 |
99.4 |
0.53 |
|
Ds-TPB |
1.52 |
99.4 |
0.36 |
98.8 |
0.53 |
99.3 |
0.43 |
99.0 |
0.81 |
|
3.03 |
99.3 |
0.55 |
98.4 |
0.38 |
99.7 |
0.56 |
99.3 |
0.77 |
|
4.55 |
99.q |
0.47 |
98.7 |
0.27 |
99.3 |
0.39 |
99.1 |
0.22 |
|
Amostigmine tablet (15 mg/tablet) Ns-ST |
|
1.52 |
99.20 |
0.53 |
102.7 |
0.63 |
99.4 |
0.76 |
99.3 |
0.52 |
|
3.03 |
101.2 |
0.48 |
102.9 |
0.39 |
100.5 |
0.58 |
99.0 |
0.63 |
|
4.55 |
99.00 |
0.36 |
99.00 |
0.26 |
100.8 |
0.37 |
100.7 |
0.39 |
|
6.06 |
102.0 |
0.78 |
101.7 |
0.31 |
101.3 |
0.56 |
101.2 |
0.60 |
|
Amostigmine injection (0.5 mg/ml) Ns-ST |
|
1.52 |
99.8 |
0.32 |
96.2 |
0.31 |
99.3 |
0.55 |
99.7 |
0.56 |
|
3.03 |
99.5 |
0.57 |
99.6 |
0.25 |
99.9 |
0.49 |
99.6 |
0.77 |
|
4.55 |
99.6 |
0.32 |
99.5 |
0.67 |
99.7 |
0.52 |
99.6 |
0.58 |
|
6.06 |
99.1 |
0.72 |
99.1 |
0.43 |
99.4 |
0.63 |
99.3 |
0.71 |
|
Spiked Urine Ns-ST |
|
1.52 |
98.6 |
0.22 |
98.0 |
0.33 |
99.0 |
0.50 |
99.1 |
0.35 |
|
3.03 |
98.7 |
0.41 |
98.4 |
0.50 |
99.0 |
0.62 |
99.3 |
0.60 |
|
4.55 |
98.3 |
0.46 |
98.1 |
0.56 |
99.0 |
0.32 |
99.0 |
0.34 |
|
Potentiometric titration: (Ns-ST) as ion-association and as titrant: |
Pure solutions |
3.03 |
100.9 |
0.19 |
102.2 |
0.11 |
100.7 |
0.33 |
101.1 |
0.13 |
|
6.06 |
101.3 |
0.22 |
102.5 |
0.31 |
100.3 |
0.21 |
101.5 |
0.22 |
|
9.09 |
101.5 |
0.26 |
102.0 |
0.33 |
100.5 |
0.14 |
100.9 |
0.61 |
|
15.16 |
101.5 |
0.20 |
102.4 |
0.50 |
100.6 |
0.17 |
101.4 |
0.18 |
|
21.22 |
101.7 |
0.44 |
102.5 |
0.46 |
100.7 |
0.33 |
101.7 |
0.24 |
|
30.32 |
100.9 |
0.51 |
102.2 |
0.37 |
100.9 |
0.41 |
101.9 |
0.26 |
|
Amostigmine tablet (15 mg/tablet) |
|
3.03 |
102.0 |
0.17 |
102.4 |
0.10 |
101.1 |
0.21 |
101.0 |
0.41 |
|
9.09 |
102.2 |
0.19 |
102.6 |
0.15 |
101.6 |
0.31 |
101.2 |
0.23 |
|
15.16 |
102.3 |
0.10 |
102.7 |
0.17 |
101.7 |
0.14 |
101.5 |
0.36 |
|
21.22 |
102.5 |
0.12 |
102.7 |
0.23 |
101.9 |
0.11 |
101.8 |
0.44 |
|
Amostigmine injection (0.5 mg/ml) |
|
3.03 |
99.8 |
0.22 |
99.0 |
0.27 |
99.3 |
0.33 |
99.8 |
0.15 |
|
9.09 |
99.7 |
0.52 |
99.1 |
0.23 |
99.6 |
0.25 |
99.5 |
0.11 |
|
15.16 |
99.3 |
0.36 |
99.0 |
0.25 |
99.5 |
0.42 |
99.2 |
0.18 |
|
21.22 |
99.0 |
0.41 |
99.1 |
0.21 |
99.7 |
0.27 |
99.4 |
0.25 |
|
Table 5: Determination of neostigmine in pure solutions, amostigmine tablet (15 mg/tablet), amostigmine injection (0.5 mg/ml) and urine by the employing the coated wires
sensors applying the standard addition method and potentiometric titration. |