Table 1 | Chromatorgraphic, UV ..

Peak No.	t_R (min)	UV λ_max (nm)	*[M+H]⁺ (m/z)*	Fragment ions (+)	*[M-H]^ˉ (m/z)*	Fragment ions (-)	Compound
1	26.66	229,275,305(sh)	ND^a	ND^a	165	150,122,107	Apocynin
2	28.57	218,319(sh)	391	ND^a	389	227,182,143	Picied
3	33.81	265,332(sh)	463	301,183,103,85	461	446,283,227,162,136	Tectoridin
4	37.59	213,263,339(sh)	463	343,329,301,286,127,109,85	461	446,283,255,239,195,167	Tectorigenin-4`-glucoside
5	38.64	215,265,339(sh)	523	361,346,310,282	521	491,359,343,313	Iridin
6	55.03	264,314	301	285,268,168,122	299	284,255,240,211,132,110	Tectorigenin
7	57.97	221,266	361	345,315,303,245,208,193,107	359	344,328,329,314,285,258,270,191	Irigenin
8	60.64	219,289,344(sh)	ND^a	ND^a	301	286,253,166,155,140,120,110,87	5,2`,3`-trihydroxy-7-methoxyflavanone
9	66.21	264,333(sh)	387	357,342,326,311,279,206, 165,132,120	ND^a	ND^a	Irisflorentin
10	67.12	224,297,348(sh)	ND^a	ND^a	313	298,224,213,192,166,138,123,110	Crocetenone
11	68.90	263,346(sh)	315	299,285,269,254,169,133	313	298,283,267,255,211,183,167,141,117	5,7-dihydroxy-6,2`-dimethoxyisoflavone

t_R: Retention time.
Sh: shoulder peak.
^aThe ion signals of this component investigated were not detected in this ion mode.

Table 1: Chromatorgraphic, UV and mass spectral characteristics of marker compounds.