Compound Name
Precursor Ion
Product Ion 1
Product Ion 2
Buprenorphine-D4
472.4
59.2
N/A
Buprenorphine
468.3
396.1
55.2
Norbuprenorphine-D3
417.3
55
N/A
Norbuprenorphine
414.3
83
55
Naltrexone-D3
345.2
N/A
N/A
Propoxyphene-D5
345.2
58.1
N/A
Naltrexol
344.2
N/A
N/A
Fentanyl-D5
342.2
105.1
N/A
Naltrexone
342.2
N/A
N/A
Propoxyphene
340.2
266.1
58.1
Zolpidem-COOH
338.2
N/A
N/A
Fentanyl
337.2
188.2
105.1
Paroxetine-D6
336.2
N/A
N/A
6-Acetylmorphine-D3
334.2
165.1
N/A
Paroxetine
330.2
N/A
N/A
α-OH-alprazolam-D5
330.2
302
N/A
6-Acetylmorphine
328.2
211.1
165.1
Norpropoxyphene
326
252
44
α-OH-alprazolam
325.1
297
216
Oxycodone-D6
322.2
247.1
N/A
Lorazepam
321
275
229
Oxycodone
316.2
256.1
241.1
Fluoxetine-D6
316.1
N/A
N/A
Zolpidem-D6
314.3
N/A
N/A
Methadone-D3
313.2
105
N/A
Methadone
310.2
265.1
105
Fluoxetine
310.1
N/A
N/A
Zolpidem
308
N/A
N/A
Codeine-D6
306.2
115
N/A
Hydrocodone-D6
306.2
202.2
N/A
Temazepam-D5
306
260
N/A
Oxymorphone-D3
305.3
201.1
N/A
Oxymorphone
302.3
227
198
Norfluoxetine-D6
302.2
N/A
N/A
Noroxycodone
302.2
284
187
Duloxetine-D3
301.2
N/A
N/A
Temazepam
301
255
177
Codeine
300.2
152
115
Hydrocodone
300.2
199?
128
Duloxetine
298.1
N/A
N/A
Norfluoxetine
296.1
N/A
N/A
Benzoylecgonine-D3
293.3
171.4
N/A
Hydromorphone-D6
292.2
128.1
N/A
Morphine-D6
292.2
152.1
N/A
Oxazepam-D5
292.1
246.1
N/A
Benzoylecgonine
290.3
168.3
105.3
Oxazepam
287
241
104
Hydromorphone
286.2
185
128.1
Morphine
286.2
165.1
152.1
Norhydrocodone
286.1
199.1
115.1
7-NH2-clonazepam
286
222
121.1
Venlafaxine-D6
284.3
N/A
N/A
Doxepin-D3
283.1
87
N/A
Amitriptyline-D3
281.2
91
N/A
EDDP-D3
281.2
234.1
N/A
Imipramine
281.1
86
58
Doxepin
280.1
107
84
Venlafaxine
278.4
N/A
N/A
Amitriptyline
278.2
105
91
EDDP
278.2
234.1
186
Cyclobenzaprine
276.2
231
191
MDPV
276.2
N/A
N/A
Nordiazepam
271
165
140
Carisoprodol-D7
268.2
183.3
N/A
Tramadol-13CD3
268.2
58.1
N/A
Desipramine
267.1
72
44
O-desmethylvenlafaxine
264.3
N/A
N/A
Nortriptyline
264.2
233
155
Tramadol
264.2
58.1
N/A
Carisoprodol
261.2
176.1
97?
Meperidine-D4
252.3
224.2
N/A
Phencyclidine-D5
249.2
86.1
N/A
Meperidine
248.3
220.3
174.2
Phencyclidine
244.2
91.1
86.1
Secobarbital-D5
244
N/A
N/A
Methylphenidate-D9
243.2
93
N/A
Ketamine-D4
242.1
224.1
N/A
Secobarbital
239
N/A
N/A
Normeperidine-D4
238.3
164.2
N/A
Norfentanyl-D5
238.2
84.1
N/A
Ketamine
238.1
125
89.1
Phenobarbital-D5
238.1
N/A
N/A
Methylphenidate
234.2
84.1
56.2
Normeperidine
234.1
188.1
160.1
Norfentanyl
233.2
84.1
56
Phenobarbital
233.1
N/A
N/A
Ritalinic acid-D10
230.2
93.1
N/A
Butalbital-D5
230
N/A
N/A
Meprobamate-D7
226.2
165.2
N/A
Butalbital
225
N/A
N/A
Norketamine
224.1
207.1
115.1
Tapentadol
222.1
107.1
77.1
Ritalinic acid
220.1
84.1
56.1
Meprobamate
219.1
158.1
69.1
Methylone-D3
211.1
N/A
N/A
Methylone
208.1
N/A
N/A
MDMA
194.1
163.1
135
Gabapentin-D10
182.1
N/A
N/A
Mephedrone-D3
181.1
N/A
N/A
Mephedrone
178.1
N/A
N/A
Gabapentin
172.1
N/A
N/A
Pregabalin-D6
166.2
N/A
N/A
Pregabalin
160.1
N/A
N/A
Methamphetamine-D5
155.1
92.1
N/A
Methamphetamine
150.1
119.1
91.1
Amphetamine-D5
141.1
124.1
N/A
Amphetamine
136.1
119.1
91.1
Table 1:
Test menu, internal standards, precursor ions, product ion one and product ion two for monitoring pain medications arranged by m/z value of the precursor ion generated in the positive mode of ESi.
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