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.com
Volume 5
Journal of Environmental Analytical Chemistry
Green Chemistry Congress 2018
July 19-20, 2018
July 19-20, 2018 Melbourne, Australia
5
th
World Congress on
Green Chemistry and Green Engineering
Preparation of cellulose modified withmetallophthalocyanines as a new biocompatible catalytic system
Mozhdeh Seyyedhamzeh
1
, Sajjad Keshipour
2
and Rana Bahluli
2
1
Kuwait University, Kuwait
2
Urmia University, Iran
H
eterogenized catalysts containing biocompatible supports green aspect of the
procedure. Using cellulose as a support in the different catalytic reactions
showed high activity of cellulose supported catalysts. Nowadays, many efforts
have been accomplished on the improvement of efficient catalytic methods using
Metallophthalocyanines (MPcs) as attractive oxidation catalysts. MPcs shows high
activity, rather facile preparation in a large scale and chemical and thermal stability. In
the present work, MPcs was immobilized on Microcrystalline Cellulose (MCC). The
prepared nanocomposite revealed good catalytic activity for the oxidation of alcohols,
ethylbenzene and styrene with high conversions. Furthermore, good selectivities have
been observed during oxidation of alcohols to the corresponding aldehydes or ketones
and also oxidation of ethylbenzene and styrene to acetophenone.
References
1.
Keshipour S and Adak K (2017) Magnetic d‐penicillamine‐functionalized cellulose as a new heterogeneous support for
cobalt(II) in green oxidation of ethylbenzene to acetophenone.
Applied Organometallic Chemistry
; DOI: 10.1002/aoc.3774.
2.
Keshipour S and Khezerloo M (2017) Gold nanoparticles supported on cellulose aerogel as a new efficient catalyst for
epoxidation of styrene.
Journal of the Iranian Chemical Society
; 14:1107-1112.
Biography
Mozhdeh Seyyedhamzeh has obtained her PhD and focused on the synthesis of organic molecules and exploring fundamental chemical principles to aid the
development of efficient synthetic methods. During her Postdoctoral research, she was interested in nano-catalysts and nano-technologies for green organic synthesis
by using nanomaterials such as carbon nanotubes and grapheme. She is also interested in synthesis of nano-biocompatible catalysts which is based on cellulose.
mojdehamze@gmail.comMozhdeh Seyyedhamzeh et al., J Environ Anal Chem 2018, Volume 5
DOI: 10.4172/2380-2391-C1-002
O
O
HO
OH
O
O
O
HO
HO
OH
OH
OH
OH
OH
OH
HO
n
O
O
HO
O
O
O
O
HO
HO
OH
OH
OH
OH
OH
OH
HO
n
N
N N
N
M
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N N
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M
HO
O
AlCl
3
Cl
OH
O
O
N
N
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M
CoPc (
3)
MCC (
1
)
Figure-1:
Preparation of catalyst.