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The description of the transfers of Volatile Organic Pollutants in the soil is an essential step for the scientific community concerning the resolution of problems related to environmental sciences. However, the prediction of the phenomena involved in the transfer of a pollutant in soil is very difficult because several processes nonlinear and coupled occur in a multiphase medium which can deform, and where the fluids content can vary with time and space. Accordingly, any model that aims to describe and to predict the dynamic behavior of a VOP in the soil in order to better track its migration during a decontamination process must be preceded by an investigation in laboratory to determine the essential parameters involved in the phenomenon.