alexa Kinetic Investigation of Nitroarylation of Pyrrole with 1-Chloro-4- Nitrobenzene Using a New Multi-Site Phase-Transfer Catalyst under Ultrasonic Condition

Our Group organises 3000+ Global Conferenceseries Events every year across USA, Europe & Asia with support from 1000 more scientific societies and Publishes 700+ Open Access Journals which contains over 50000 eminent personalities, reputed scientists as editorial board members.

Recommended Conferences

Clinical Oncology & Radiation Therapy

Singapore, Singapore
Kinetic Investigation of Nitroarylation of Pyrrole with 1-Chloro-4- Nitrobenzene Using a New Multi-Site Phase-Transfer Catalyst under Ultrasonic Condition

In the present research work, the solid-liquid reaction was successfully carried out in the new synthesized multisite phase-transfer catalyst, namely i.e., 1,3,5-tribenzyl-1,3,5-triethyl-1,3,5-triazinane-1,3,5-triium trichloride(MPTC), and sonication (40 kHz, 300 W) to produce the desired product namely 1-(4-nitropheny) pyrrole from pyrrole and 4-nitrochlorobenzene. The selectivity of N-arylation product was obtained under sonication and MPTC. The combination of ultrasound and MPTC resulted in better efficacy as compared to the individual operations. The apparent reaction rate is greatly enhanced and observed to obey the pseudo-first order kinetics. The kapp value increases with increasing kinetic parameters that is the amount of [MPTC], [substrate], ultrasonication, stirring speed, temperature, etc.

Citation: Selvaraj V, Harikumar K, Sathiyaraj M, Rajendran V (2015) Kinetic Investigation of Nitroarylation of Pyrrole with 1-Chloro-4-Nitrobenzene Using a New Multi-Site Phase-Transfer Catalyst under Ultrasonic Condition. Chem Sci J 6:104. doi:10.4172/2150-3494.1000104

  • Share this page
  • Facebook
  • Twitter
  • LinkedIn
  • Google+
  • Pinterest
  • Blogger
Top