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http://www.sciencedirect.com/science/article/pii/S000398610700094X
Free zinc ions are potent effectors of proteins. Their tightly controlled fluctuations (“zinc signals”) in the picomolar range of concentrations modulate cellular signaling pathways. Sulfur (cysteine) donors generate redox-active coordination environments in proteins for the redox-inert zinc ion and make it possible for redox signals to induce zinc signals.
Courtesy: Artur et al., 2007
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