Effect Of Sulfate And Chloride Salts On Coal Biodesulfurization Process Employing Acidophilic Bacteria | 17067
Journal of Biotechnology & Biomaterials
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Reducing sulfur from coal before combustion seeks to limit the amount of pollutant SOx gases emitted to the atmosphere.
Among the different kinds of coal desulfurization, biological processes have many economic and environmental advantages
in comparison to chemical and physical processes. Among the different important parameters to develop a profitable process,
sulfate precipitates (as jarosite) on the surface of mineral should be avoided because it affects the mass transfer in the process.
The present work evaluated the behavior of two cultures, a pure strain (Acidithiobacillus ferrooxidans) and a consortium (A.
ferrooxidans and A. thiooxidans), in coal biodesulphurization processes for five different culture media, three based on sulfate
salts and two based chloride salts. Coal (particle size < 0.25mm) came from the ?Guacamaya? mine (C?rdoba, Colombia). All
the experiments were monitored by chemical measurements of pH, redox potential, iron, pyrite and cell concentration, and
mineralogical analyses of X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and Scanning electron
microscopy (SEM). The assays revealed the both cultures were capable to carry out the process by using low concentrations
of nutrients and without a magnesium source. All assays obtained a pyrite oxidation around 80% after 15 days of the process.
However, the assays using sulfate medium had the lowest sulfate precipitation, agreeing with the found in previous researches
reported in the literature.
Duarte Paola is a biological Engineer currently pursuing a Master of Science- Biotechnology at the National University of Colombia. She is a Researcher of
Bioprocess and Applied Mineralogy Group (GMAB) of this university, and she has published a paper in the Colombian Magazine of biotechnology.
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